An amino acid coordinated vanadium (IV) complex: Synthesis, structure, DFT calculations and VHPO mimicking catalytic bromoperoxidation of organic substrates

U Saha, TK Si, PK Nandi, KK Mukherjea

文献索引：Saha, Urmila; Si, Tapan Kr.; Nandi, Prasanta Kr.; Mukherjea, Kalyan K. Inorganic Chemistry Communications, 2013 , vol. 38, p. 43 - 46

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被引用次数: 16

摘要

Abstract A new VHPO mimicking oxovanadium (IV) complex [VO (sal-l-val)(phen)](sal-l-val= Schiff base derived from salicylaldehyde and l-valine; phen= 1, 10-phenanthroline) has been synthesized and characterized by elemental analysis, UV–vis, IR spectroscopy, ESI- MS, EPR and single crystal XRD studies. The structural and spectral parameters were further supported using DFT calculations. The complex was found to exhibit vanadium ...