Silica-and polymer-supported platinum (II) polypyridyl complexes: synthesis and application in photosensitized oxidation of alkenes

K Feng, ML Peng, DH Wang, LP Zhang, CH Tung…

文献索引：Feng, Ke; Peng, Ming-Li; Wang, Deng-Hui; Zhang, Li-Ping; Tung, Chen-Ho; Wu, Li-Zhu Dalton Transactions, 2009 , # 44 p. 9794 - 9799

全文：HTML全文

被引用次数: 7

摘要

Square-planar polypyridine platinum (II) complexes have been introduced into a silica/polymer matrix by covalent ligand modification. The photophysical properties of the supported matrices are well retained as their model complexes, and the quantum yields for singlet oxygen (1O2) generation are comparable with that of TPP (tetraphenylporphyrin) under similar conditions. A preliminary application in photosensitized oxidation indicates ...