The reaction between alkali metal alkyls and quaternary arsonium compounds

MEP Friedrich, CS Marvel

文献索引：Friedrich; Marvel Journal of the American Chemical Society, 1930 , vol. 52, p. 383

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被引用次数: 29

摘要

In some of the early work on organic arsenic compounds Cahours' reported the preparation of pentamethylarsine by the action of zinc dimethyl on tetramethylarsonium iodide. The evidence for the existence of this penta-alkylarsine was slight and the work has never been confirmed. Previous attempts in this Laboratory to prepare the analogous penta-alkyl nitrogen2 and phosphorus3 compounds by the action of alkali metal alkyls on the ...