Journal of the American Chemical Society

Extending the scope of enantiomer resolution by complexation gas chromatography

V Schurig, W Buerkle

文献索引：Schurig,V.; Buerkle,W. Journal of the American Chemical Society, 1982 , vol. 104, p. 7573

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被引用次数: 198

摘要

Abstract: Nickel (I1) bis [(1R)-3-(heptafluorobutyryl) camphorate](3b) is an efficient optically active stationary phase for the quantitative gas chromatographic resolution of racemic alkyl- substituted cyclic ethers containing rings of up to six members (6-16), the cyclic ketone trans- 2, 5-dimethylcyclopentanone (19), and the aliphatic alcohol tert-butylmethylcarbinol (20). Thermodynamic parameters of enantiomer discrimination, Le.,-AsR (AGo), between ten ...