A novel mode of access to polyfunctional organotin compounds and their reactivity in Stille cross-coupling reaction

S Lamandé-Langle, M Abarbri, J Thibonnet…

文献索引：Lamande-Langle, Sandrine; Abarbri, Mohamed; Thibonnet, Jerome; Duchene, Alain Journal of Organometallic Chemistry, 2009 , vol. 694, # 15 p. 2368 - 2374

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被引用次数: 5

摘要

Mono-, di-, tri-and tetra-functional organotin compounds were easily prepared in a sonicated Barbier reaction using ultrasound technology via coupling reaction of organo halides with tin halides (Bu3SnCl, Bu2SnCl2, BuSnCl3, SnCl4) mediated by magnesium metal. The di-and tri-functional organotin compounds were tested in a Stille cross-coupling reaction in order to ascertain how many groups were transferred.

~85%

21651-12-7

(E)-戊-2,4-二烯酸

~72%

~59%

~39%

~49%

~90%

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