The Journal of Physical Chemistry

Laser flash photolysis study of the effects of substituents, solvents, and quenchers on the triplet state of benzaldehydes. Hydrogen/deuterium exchange following …

H Gorner, HJ Kuhn

文献索引：Gorner, Helmut; Kuhn, Hans Jochen Journal of Physical Chemistry, 1986 , vol. 90, # 22 p. 5946 - 5955

全文：HTML全文

被引用次数: 20

摘要

The deactivation pathways of the lowest triplet state of benzaldehyde (BA), a series of substituted derivatives (OCH3, CH3, F, C1, Br, CHO, and CN), and some related aromatic aldehydes were examined at room temperature by laser flash photolysis in several solvents including water. The triplet state (Lx= 325 nm for BA in acetonitrile) was identified by energy- transfer measurements. All benzaldehydes studied exhibit phosphorescence in glassy ...