The Journal of organic chemistry

N-isopropylidene-N'-2-nitrobenzenesulfonyl hydrazine, a reagent for reduction of alcohols via the corresponding monoalkyl diazenes

M Movassaghi, OK Ahmad

文献索引：Movassaghi, Mohammad; Ahmad, Omar K. Journal of Organic Chemistry, 2007 , vol. 72, # 5 p. 1838 - 1841

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被引用次数: 44

摘要

The reagent N-isopropylidene-N'-2-nitrobenzenesulfonyl hydrazine (IPNBSH) is used in the reduction of alcohols via the loss of dinitrogen from transiently formed monoalkyl diazene intermediates accessed by sequential Mitsunobu displacement, hydrolysis, and fragmentation under mild reaction conditions.