Generation and recycle use of selenenylating reagents in electrochemical oxyselenenylation-deselenenylation of olefins

…, K Uneyama, M Ono, T Bannou

文献索引：Torii, Sigeru; Uneyama, Kenji; Ono, Michio; Bannou, Tadashi Journal of the American Chemical Society, 1981 , vol. 103, # 15 p. 4606 - 4608

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被引用次数: 61

摘要

Oxy seleneny lation-xidative deselenenylation sequence provides double-bond transpositioned allylic alcohols and ethers from o1efins. I The current method involves two steps: oxyselenenylation with PhSeX (X= C1, Br, OR, and NR2) followed by oxidation with 03, NaIO,, and peroxides (H202, t-BuOOH, m-CPBA) where stoichiometric amounts of PhSeX in the former step and large excess amount of oxidative reagents in the latter are ...