Journal of Organometallic Chemistry

Cyclometalated gold (III) iminophosphoranes which incorporate carbohydrate groups

BP Jarman, BK Nicholson

文献索引：Jarman, Bevan P.; Nicholson, Brian K. Journal of Organometallic Chemistry, 2012 , vol. 702, p. 1 - 9

全文：HTML全文

被引用次数: 3

摘要

Iminophosphoranes with organic groups derived from d-glucose, d-galactose and l- arabinose have been used to prepare gold (III) dichloride complexes via mercurated intermediates, since direct cyclometallation was unsuccessful. Structures and full spectroscopic data are reported. Replacement of one or more of the chloride ligands by PPh3, or by thiosalicylate gave new derivatives. Biological screening showed no ...