The Grignard Reaction in the Synthesis of Ketones. II. The Preparation of a Series of Mono-and Di-chlorodesoxybenzoins

SS Jenkins, EM Richardson

文献索引：Jenkins; Richardson Journal of the American Chemical Society, 1933 , vol. 55, p. 1618,1619

全文：HTML全文

被引用次数: 11

摘要

In the preceding article1 a new method of synthesizing desoxybenzoins (benzylphenyl ketones) by means of the Grignard reaction was described. It was found that these compounds could be prepared by the reaction of benzylmagnesium halides with primary benzamides and that quite satisfactory yields were obtained when the reactants, in the ratio of three to four equivalents of the former to one of the latter, were heated over suf-ficiently ...