Synthesis

Synthesis of Alkenylboronates via Palladium-Catalyzed Borylation of Alkenyl Triflates (or Iodides) with Pinacolborane

M Murata, T Oyama, S Watanabe, Y Masuda

文献索引：Murata, Miki; Oyama, Takashi; Watanabe, Shinji; Masuda, Yuzuru Synthesis, 2000 , # 6 p. 778 - 780

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被引用次数: 47

摘要

Abstract: Various alkenyl iodides and triflates were borylated with pinacolborane in the presence of Et3N and a catalytic amount of PdCl2 (dppf) and AsPh3 to afford the corresponding alkenylboronates in good yields. Key words: boron, hydrides, palladium, halides, cross-coupling, triflates