Journal of Molecular Catalysis A: Chemical

Macroporous resin impregnated palladium nanoparticles: Catalyst for a microwave-assisted green Hiyama reaction

D Shah, H Kaur

文献索引：Shah, Dipen; Kaur, Harjinder Journal of Molecular Catalysis A: Chemical, 2012 , vol. 359, p. 69 - 73

被引用次数: 16

摘要

A non-functional macroporous commercial resin, Amberlite XAD-4, was impregnated with palladium nanoparticles of size 5–10nm. The supported PdNPs, thus prepared, were used to catalyze the sodium hydroxide activated Hiyama cross-coupling reaction of phenyltrimethoxysilane with a variety of bromo and chloro arenes under microwave heating. They were found to have very high efficiency (TOF≈ 3× 104) and excellent recyclability. ...

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