The hydroxyl radical reaction rate constant and atmospheric transformation products of 2??propoxyethanol

SJ Markgraf, J Semples, JR Wells

文献索引：Markgraf, Stewart J.; Semples, John; Wells International Journal of Chemical Kinetics, 1999 , vol. 31, # 4 p. 315 - 322

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被引用次数: 8

摘要

Abstract The relative rate technique has been used to measure the hydroxyl radical (OH) reaction rate constant of 2-propoxyethanol (2PEOH, CH 3 CH 2 CH 2 OCH 2 CH 2 (OH)). 2PEOH reacts with OH with a bimolecular rate constant of (21.4±6.0)× 10− 12 cm 3 molecule− 1 s− 1 at 297±3 K and 1 atm total pressure, which is a little larger than previously reported [1]. Assuming an average OH concentration of 1× 10 6 molecules cm− 3, an ...