C??nitroso compounds. Part XII: Cis??and trans??azodioxy compounds (dimeric nitroso compounds) by photochemical nitrosation of hydrocarbons with tert??butyl nitrite
A Mackor, TJ De Boer
文献索引：Mackor,A.; de Boer,T.J. Recueil des Travaux Chimiques des Pays-Bas, 1970 , vol. 89, p. 151 - 158
Abstract The photochemical nitrosation of (cyclo) alkanes and alkylbenzenes, containing abstractable primary or secondary hydrogen atoms, with t-butyl nitrite has been carried out at 0-5 C using wavelengths around 400 nm. The main products are trans-azodioxy compounds (trans-dimeric nitroso compounds), derived from the solvent and the corresponding oximes in (total) yields, ranging from 55-80%. At low temperature or with ...
