Stereognostic coordination chemistry. 1. The design and synthesis of chelators for the uranyl ion

…, KR Czerwinski, KN Raymond

文献索引：Franczyk, Thaddeus S.; Czerwinski, Kenneth R.; Raymond, Kenneth N. Journal of the American Chemical Society, 1992 , vol. 114, # 21 p. 8138 - 8146

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被引用次数: 105

摘要

Abstract: A new approach to the molecular recognition of metal oxo cations is introduced based on a ligand design strategy that provides at least one hydrogen bond donor for interaction with oxo group@) as well as conventional electron pair donor ligands for coordination to the metal center. This concept of stereognostic coordination of oxo metal ions is exemplified in the design of four tripodal ligands-tris [2-(2-carboxyphenoxy) ethyl] ...