An improved procedure for the synthesis and use of [RuCl2 (BINAP)] 2. cntdot. NEt3. Dependence of the ruthenium (II)-BINAP catalyzed asymmetric hydrogenation of. …

…, AS Thompson, AO King, TR Verhoeven

文献索引：King, Steven A.; Thompson, Andrew S.; King, Anthony O.; Verhoeven, Thomas R. Journal of Organic Chemistry, 1992 , vol. 57, # 25 p. 6689 - 6691

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被引用次数: 119

摘要

(20) Alternatively, there t a chance that AMTMS t acting a~ a 'slow substrate" (ki t then just km), the recovery of enzyme activity resulting from eventual turnover to noninhibiting produds. (21) The recovery of activity for enzyme inactivated with 100 pM AMTMS occurred with rates of 0.0099,0.020, and 0.036 mid at 5,10, and 30 OC. (22) No alteration of the activiiy-time profile was observed wing lower concentrations of KF or KCl and/or when the reactions ...