N–H insertion reactions of rhodium carbenoids. Part 2. Preparation of N-substituted amino (phosphoryl) acetates (N-substituted phosphorylglycine esters)

L Ferris, D Haigh, CJ Moody

文献索引：Ferris, Leigh; Haigh, David; Moody, Christopher J. Journal of the Chemical Society - Perkin Transactions 1, 1996 , # 24 p. 2885 - 2888

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被引用次数: 57

摘要

Rhodium () acetate-catalysed reaction of ethyl 2-diazo-2-diethoxyphosphorylacetate 2 with carbamates, amides, ureas or anilines gives a range of-substituted 2-amino-2- diethoxyphosphorylacetates 3–18 by NH insertion reaction of the intermediate rhodium carbenoid.