Copper??Catalyzed Aromatic C H Bond Cyanation by C CN Bond Cleavage of Inert Acetonitrile

X Kou, M Zhao, X Qiao, Y Zhu, X Tong…

文献索引：Kou, Xuezhen; Zhao, Mengdi; Qiao, Xixue; Zhu, Yamin; Tong, Xiaofeng; Shen, Zengming Chemistry - A European Journal, 2013 , vol. 19, # 50 p. 16880 - 16886

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被引用次数: 40

摘要

Acetonitrile is a common solvent in organometallic chemistry, which can coordinate to a metal center as a weak ligand. The acetonitrile CÀCN bond is usually inert to transition metals because it has a rather strong CÀCN bond energy (133 kcalmolÀ1) compared to an alkane CÀC bond energy (ca. 83 kcalmolÀ1). Accordingly, acetonitrile CÀCN bond cleavage mediated by transition metals has rarely been explored.[1] However, if acetonitrile, the ...