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Benzocrown derivatives as ionophores for alkali cations, II. Synthesis and comparison of urethane??, ether??, and ester??linked bis??crown compounds and several „ …

L Tőke, I Bitter, B Ágai, Z Hell, E Lindner…

文献索引:Toeke, Laszlo; Bitter, Istvan; Agai, Bela; Hell, Zoltan; Lindner, Ernoe; et al. Liebigs Annalen der Chemie, 1988 , p. 549 - 554

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摘要

Abstract Nitro derivatives of bis-crown ethers with urethane (2), ether (10), and ester (9, 16) linkage not being able to form hydrogen bridges were synthesized, and their K+ selectivities were determined. A remarkable effect of the NO 2 group on the selectivity was observed when a NO 2… NH hydrogen bond could be formed while the others showed only slight improvement in general electroanalytical parameters. Several analogues without the ...