Dalton Transactions

Tricyclohexylphosphine-cyclopalladated ferrocenylimine complexes: synthesis, crystal structures and application in Suzuki and Heck reactions

C Xu, JF Gong, SF Yue, Y Zhu, YJ Wu

文献索引：Xu, Chen; Gong, Jun-Fang; Yue, Su-Fang; Zhu, Yu; Wu, Yang-Jie Dalton Transactions, 2006 , # 39 p. 4730 - 4739

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被引用次数: 49

摘要

A series of novel tricyclohexylphosphine (PCy3)-cyclopalladated ferrocenylimine complexes 2c–2g have been easily synthesized. These new palladacycles are thermally stable and are not sensitive to air and moisture. Their detailed structures have been determined by single- crystal X-ray analysis and six different types of intermolecular hydrogen bonds are found to be existed in the crystals of these complexes. The use of 2c–2g as catalysts for Suzuki and ...