An efficient procedure for the TEMPO-catalyzed oxidation of alcohols to aldehydes and ketones using ferric chloride hexahydrate as terminal oxidant

…, K Karthikeyan, PT Perumal

文献索引：Kumar, R. Senthil; Karthikeyan; Perumal, Paramasivan T. Canadian Journal of Chemistry, 2008 , vol. 86, # 7 p. 720 - 725

全文：HTML全文

被引用次数: 10

摘要

A simple, efficient procedure for the oxidation of alcohols by catalytic 2, 2, 6, 6-tetramethyl- piperidyl-1-oxy (TEMPO) was developed using FeCl3⊙ 6H2O as the terminal oxidant. The reaction gives high yield of the corresponding aldehydes and ketones with no over oxidation to the acid. Key words: oxidation, TEMPO, FeCl3⊙ 6H2O.