Effect of substituents on the rate of oxidation of anilines with peroxomonosulfate monoanion (HOOSO− 3) in aqueous acetonitrile: A mechanistic study
S Meenakshisundaram, M Selvaraju…
文献索引：Meenakshisundaram, Subbiah; Selvaraju; Made Gowda; Rangappa, Kanchugarakoppal S. International Journal of Chemical Kinetics, 2005 , vol. 37, # 11 p. 649 - 657
The oxidation of amines to their oxygenated derivatives is an important industrial reaction and particularly, the reactions of aromatic amines by peroxidic reagents have received considerable attention. Recently, we embarked on the investigation of the kinetics of reaction involving substituted anilines and peroxomonosulfate monoanion with the view of probing their mechanisms. Thus far, the kinetics of oxidation of substituted anilines by HOOSO − 3 in basic medium 1 and ...
