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Canadian Journal of Chemistry

Carbocyclic phenylaminephosphonate stereochemistry as probed via 13C nmr chemical shifts and nuclear spin couplings from 13C to 31P and 15N

GW Buchanan, FG Morin

文献索引:Buchanan, Gerald W.; Morin, Frederick G. Canadian Journal of Chemistry, 1980 , vol. 58, p. 530 - 536

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被引用次数: 5

摘要

13C nmr chemical shifts and 13C-31P couplings through one, two, and three bonds are reported for eleven carbocyclic phenylaminephosphonates with ring sizes from four to seven. On the basis of these data, inferences regarding preferred conformations are drawn. Low temperature spectra of the 4-methylcyclohexyl derivative show the existence of two conformers, populated in the ratio of approximately 2: 1 at 183 K.