Phase-transfer catalysis by poly (ethylene glycol) s of. beta.-thioethyl chloride reactions

JM Harris, MS Paley, MR Sedaghat-Herati…

文献索引：Harris, J. Milton; Paley, M. Steven; Sedaghat-Herati, M. R.; McManus, Samuel P. Journal of Organic Chemistry, 1985 , vol. 50, # 25 p. 5230 - 5233

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被引用次数: 12

摘要

Neighboring sulfur participation is a facile process for P-thioethyl derivatives. In the present work we examine the ability of phase-transfer catalysis by poly (ethy1ene glyco1) s to make direct substitution, elimination, and oxidation competitive with neighboring sulfur participation for reaction of mustard chlorohydrin (1).