Development of a catalytic electron transfer system mediated by transition metal ate complexes: Applicability and tunability of electron-releasing potential for organic …

…, N Kobayashi, N Yamashita, A Matsumiya…

文献索引：Uchiyama, Masanobu; Matsumoto, Yotaro; Nakamura, Shinji; Ohwada, Tomohiko; Kobayashi, Nagao; Yamashita, Natsuno; Matsumiya, Atsushi; Sakamoto, Takao Journal of the American Chemical Society, 2004 , vol. 126, # 28 p. 8755 - 8759

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被引用次数: 42

摘要

We have developed a catalytic electron transfer (ET) system composed of a transition metal ate complex (Me3M (II) Li; M= Co (II), Mn (II), Fe (II)) and magnesium. This system (catalytic Me3M (II) Li/Mg) turned out to be effective for various ET reactions, such as the desulfonylation of N-phenylsulfonyl amides, and others (the chemoselective cleavage of O- allyl groups, the reduction of nitro groups, the partial reduction of diketones, and the ...