Tetrahedron letters

A remarkably simple α-oximation of ketones to 1, 2-dione monooximes using the chlorotrimethylsilane–isoamyl nitrite combination

AHA Mohammed, G Nagendrappa

文献索引：Mohammed, Abdulkarim H.A.; Nagendrappa, Gopalpur Tetrahedron Letters, 2003 , vol. 44, # 13 p. 2753 - 2755

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被引用次数: 18

摘要

Download PDF Opens in a new window. Article suggestions will be shown in a dialog on return to ScienceDirect. ... Please enable JavaScript to use all the features on this page. ... Ketones undergo α-oximation by NOCl formed in situ from Me 3 SiCl and isoamyl nitrite, either in solution or under solvent-free conditions, to produce 1,2-dione monooximes in excellent yields. The oximation is regiospecific in appropriate cases. ... We have found that ketones undergo α-oximation ...