The Journal of Organic Chemistry

Arylation of several carbanions by the SRN1 mechanism

RA Rossi, JF Bunnett

文献索引：Rossi,R.A.; Bunnett,J.F. Journal of Organic Chemistry, 1973 , vol. 38, p. 3020 - 3025

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被引用次数: 56

摘要

The carbanions derived from 1, 3-pentadiene, l-(p-anisyl) propene, indene, fluorene, 2- butanone, and 3-methyl-2-butanone are phenylated by treating them with bromobenzene and sodium or potassium metal in liquid ammonia. The enolate ions of the two ketones are also phenylated by photostimulated reaction with bromo-or iodobenxene. By either method, 2-butanone is phenylated principally at the 3 position and 3-methyl-2-butanone mainly at ...