Journal of organometallic chemistry

Cyclic voltammetry of arylferrocenes and ferrocene analogues of chalcones. Substituent effects on the electron density distribution in ferrocene derivatives

AG Nagy, S Toma

文献索引：Nagy, Agnes G.; Toma, Stefan Journal of Organometallic Chemistry, 1984 , vol. 266, # 3 p. 257 - 268

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摘要

Cyclic voltammetry studies of arylferrocenes and two series of ferrocene analogues of chalcone are presented. Good correlations of the oxidation potentials (E ) with the σ Hammett constants as well as with the 13 C chemical shifts for carbon atoms with different positions in the ferrocenyl moiety have been found. The different sensitivities of these series to the substituent effects is discussed. The variation of the electron density distribution at the carbon atoms of the ...