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Copper-catalyzed aerobic aliphatic C–H oxygenation with hydroperoxides

PC Too, YL Tnay, S Chiba

文献索引:Too, Pei Chui; Tnay, Ya Lin; Chiba, Shunsuke Beilstein Journal of Organic Chemistry, 2013 , vol. 9, p. 1217 - 1225

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被引用次数: 8

摘要

Abstract We report herein Cu-catalyzed aerobic oxygenation of aliphatic C–H bonds with hydroperoxides, which proceeds by 1, 5-H radical shift of putative oxygen-centered radicals (O-radicals) derived from hydroperoxides followed by trapping of the resulting carbon- centered radicals with molecular oxygen.

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