Tetrahedron

Dimerization of anilines and benzylamines with mercury (II) oxide-iodine reagent

K Orito, T Hatakeyama, M Takeo, S Uchiito, M Tokuda…

文献索引：Orito, Kazuhiko; Hatakeyama, Takahiro; Takeo, Mitsuhiro; Uchiito, Shiho; Tokuda, Masao; Suginome, Hiroshi Tetrahedron, 1998 , vol. 54, # 29 p. 8403 - 8410

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被引用次数: 75

摘要

By treatment with mercury (II) oxide-iodine reagent in dichloromethane at room temperature, substituted anilines were transformed to the corresponding azobenzenes. A similar treatment of benzylamines and benzhydrylamine gave N-benzylidenebenzylamines and N- benzhydrylidenebenzhydrylamine, respectively. α-Alkyl-substituted benzylamines gave diazenes and the corresponding phenyl ketones, competitively. An azine was obtained by ...