The Reaction of t-Butylethylene and 1-Hexene with Bromine in Methanol1a

WH Puterbaugh, MS Newman

文献索引：Puterbaugh; Newman Journal of the American Chemical Society, 1957 , vol. 79, p. 3469

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被引用次数: 23

摘要

The addition of bromine in methanol to t-butylethylene produces 1, 2-dibromo-3, 3- dimethylbutane(IV) and 2-bromo-lmethoxy-3, 3-dimethylbutane (VI) in roughly equal amounts. The addition of bromine in methanol to 1-hexene produces about 31% of 1, 2- dibromohexane and 59y0 of a mixture of 1-bromo-2-methoxyhexane and 2-bromo-1- methoxyhexane in the ratio four-to-one, respectively. The mechanism of these reactions is ...