前往化源商城

Oxidation of some α??hydroxy acids by tetraethylammonium chlorochromate: A kinetic and mechanistic study

P Swami, D Yajurvedi, P Mishra…

文献索引:Swami, Preeti; Yajurvedi; Mishra; Sharma, Pradeep K. International Journal of Chemical Kinetics, 2010 , vol. 42, # 1 p. 50 - 55

全文:HTML全文

被引用次数: 18

摘要

Abstract The oxidation of glycolic, lactic, malic, and a few substituted mandelic acids by tetraethylammonium chlorochromate (TEACC) in dimethylsulfoxide leads to the formation of corresponding oxoacids. The reaction is first order each in TEACC and hydroxy acids. Reaction is failed to induce the polymerization of acrylonitrile. The oxidation of α- deuteriomandelic acid shows the presence of a primary kinetic isotope effect (k H/k D= ...