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Synthesis of cyclopropylmethanol derivatives bearing electronegative substituents

KG Taylor, VN Nichols, R Isaac…

文献索引:Taylor,K.G. et al. Journal of Organic Chemistry, 1974 , vol. 39, # 12 p. 1761 - 1763

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被引用次数: 5

摘要

In this note we report a convenient synthesis of cyclopropylmethanol acetates bearing electron-withdrawing substituents at the 1 position. The data base for cyclopropylcarbinyl cation chemistry, for example, is provided in overwhelming part by experiments performed on carbon skeletons carrying electron-donating substituents. 2 Recent studies in the bicyclo [2.2. l] heptyl system have highlighted some interesting effects of electronegative ...