Reaction of (9-anthryl) arylmethyl chlorides with Grignard and lithium reagents

M Takagi, M Nojima, S Kusabayashi

文献索引：Takagi, Masato; Nojima, Masatomo; Kusabayashi, Shigekazu Journal of the American Chemical Society, 1982 , vol. 104, # 6 p. 1636 - 1643

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被引用次数: 7

摘要

Conclusions (1) Exchange of quinuclidine between the free and bound state takes place via an associative mechanism.(2) Except for Bleaney's T2 term there are considerable contributions of higher order T*(n 2 3) terms to the experimental pseudocontact shifts.(3) Pseudocontact shifts obtained from the slow-exchange region of NMR spectra are preferable to fast-exchange data in order to get structural information about the complex.(4 ...