Copper (I) Chloride??Catalyzed Three??Component Coupling Reaction of Primary Amines with Electrophiles and α??Halogen??Substituted Allylsilanes to Form …

M Kozuka, A Inoue, T Tsuchida…

文献索引：Kozuka, Makoto; Inoue, Akihiko; Tsuchida, Teruko; Mitani, Michiharu Advanced Synthesis and Catalysis, 2006 , vol. 348, # 7-8 p. 953 - 966

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被引用次数: 4

摘要

Abstract Tertiary amines with three different substituents, in one of which a vinylsilane functionality was included, were straightforwardly formed by the copper (I) chloride- catalyzed tandem reaction of primary amines, α-halogen-substituted allylsilanes, and electrophiles such as electron-deficient olefins, alkyl halides, alkyl tosylates, or epoxides. In the case using electron-deficient olefins as the electrophile, the addition of chloroacetone ...