Highly Regioselective Copper??Catalyzed Benzylic C H Amination by N??Fluorobenzenesulfonimide

…, Y Zheng, Y Li, H Zhang, J Zhang, Q Liu

文献索引：Ni, Zhikun; Zhang, Qian; Xiong, Tao; Zheng, Yiying; Li, Yan; Zhang, Hongwei; Zhang, Jingping; Liu, Qun Angewandte Chemie - International Edition, 2012 , vol. 51, # 5 p. 1244 - 1247

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被引用次数: 96

摘要

Amines are ubiquitous in both naturally occurring and manmade compounds which demonstrate high levels of biological activity.[1, 2] Direct construction of a CÀN bond through CÀH amination is one of the most exciting and challenging fields in amine chemistry.[3, 4] Direct aliphatic CÀH amination has led to significant results arising from the discovery of metal nitrenoids,[5–8] but highly active free nitrene is unselective and uncontrollable. ...