Dichlorodiazirine: A nitrogenous precursor for dichlorocarbene

G Chu, RA Moss, RR Sauers

文献索引：Chu, Gaosheng; Moss, Robert A.; Sauers, Ronald R. Journal of the American Chemical Society, 2005 , vol. 127, # 41 p. 14206 - 14207

全文：HTML全文

被引用次数: 21

摘要

The reaction of 3-p-nitrophenoxy-3-chlorodiazirine with a 1.1: 1.0: 1.6 blend of tetrabutylammonium chloride, cesium chloride, and the ionic liquid 1-butyl-3- methylimidazolium chloride at 40-50° C under vacuum at 1 mm⊙ Hg produced a melt from which dichlorodiazirine distilled into a cold trap containing pentane at-70° C over 6-7 h. Dichlorodiazirine, the first nitrogenous precursor for dichlorocarbene, was reasonably ...