Selective benzylic C–C coupling catalyzed by a bioinspired dicopper complex

A Prokofieva, AI Prikhod'ko, S Dechert…

文献索引：Prokofieva, Angelina; Prikhod'ko, Alexander I.; Dechert, Sebastian; Meyer, Franc Chemical Communications, 2008 , # 8 p. 1005 - 1007

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被引用次数: 12

摘要

A highly preorganized bioinspired dicopper complex with imidazole ligation catalyzes the selective benzylic para-C–H activation of 2, 4, 6-trimethylphenol under aerobic conditions, yielding either the stilbenequinone or 4-methoxymethyl-2, 6-dimethylphenol depending on the solvent used.