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Tetrahedron

Photoinduced reactions—XXXV: The hydroxylation of phenols by the photodecomposition of hydrogen peroxide in acetonitrile

K Omura, T Matsuura

文献索引:Omura,K.; Matsuura,T. Tetrahedron, 1970 , vol. 26, p. 255 - 265

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被引用次数: 16

摘要

Acetonitrile was found to be the best organic solvent for the preparative scale-hydroxylation of various phenols by the photodecomposition of hydrogen peroxide. Irradiation of the system with the light at 2537 Å resulted in the formation of ortho-and para-dihydroxy compounds as the main product. Relative reactivity of representative substituted phenols and the effect of the phenols on the decomposition rate of hydrogen peroxide were ...