Some caged oxaazaphosphoranes

DB Denney, DZ Denney, DM Gavrilovic…

文献索引：Denney,D.B.; Denney,D.Z.; Gavrilovic,D.M. Journal of the American Chemical Society, 1980 , vol. 102, p. 7072

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被引用次数: 24

摘要

This monomer on standing polymerizes rapidly and reversibly. The monomer has been allowed to react with biacetyl and benzil to give the mixed oxyazaphosphoranes 13 and 14. Variable-temperature I3C NMR studies show that these materials do not undergo rapid intramolecular ligand reorganization nor do they undergo rapid intermolecular reorganization. In the case of 14 it remains rigid up to 95 OC. 2, 10-Dimethyl-2, 6, 10-triaza ...