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Synthesis, structure, and properties of pentathiepins

…, RL Harlow, AL Johnson, SA Vladuchick

文献索引:Chenard; Harlow; Johnson; Vladuchick Journal of the American Chemical Society, 1985 , vol. 107, # 13 p. 3871 - 3879

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被引用次数: 129

摘要

Abstract: A series of aromatic and heteroaromatic fused pentathiepins has been prepared by several methods. The X-ray structure analysis of several of these compounds has been obtained along with other useful characterization data (laser Raman, UV, etc.). Certain benzopentathiepins can be made to disproportionate into sulfur and benzotrithioles. In one case (6-(trifluoromethyl) benzopentathiepin, Sc), an apparent equilibrium is established ...