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Canadian journal of chemistry

Novel electrophilic ipso acylation-detosylation reaction of pyrroles

ET Pelkey, GW Gribble

文献索引:Pelkey, Erin T.; Gribble, Gordon W. Canadian Journal of Chemistry, 2006 , vol. 84, # 10 p. 1338 - 1342

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被引用次数: 5

摘要

A pyrrole and two pyrroloindoles that are substituted with ap-toluenesulfonyl group undergo an ipso acylation-detosylation reaction with acid chlorides and aluminum chloride to afford the corresponding acyl-substituted pyrroles and pyrroloindoles. Key words: pyrrole, pyrroloindole, ipso acylation, detosylation, Friedel-Crafts reaction.