The Journal of Organic Chemistry

Some reactions of p-toluenesulfonyl isocyanate

C King

文献索引：King,C. Journal of Organic Chemistry, 1960 , vol. 25, p. 352 - 356

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被引用次数: 66

摘要

Several new reactions of p-toluenesulfonyl isocyanate (I) are reported. Reaction with N, N- dialkylamides gives N, N-dialkyl-N'-p-toluenesulfonylamidines (11), with elimination of carbon dioxide. Monoalkylamides give rise to N-alkyl-N-acyl-N'-p-toluenesulfonylureas (111) by simple addition, or to N-alkyl-N'-p-toluenesulfonylamidines (IV), with elimination of carbon dioxide. Isobutyraldehyde reacts to give VI. Dimethyl sulfoxide yields Np- ...