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The Journal of Organic Chemistry

Cyclizations Leading to 3-Anilinohydantoin1

HB Milne, DW Fish

文献索引:Milne,H.B.; Fish,D.W. Journal of Organic Chemistry, 1962 , vol. 27, p. 3177 - 3182

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被引用次数: 3

摘要

The structure of N-carboxyphenylhydrazido-glycine (IV) is based on the following evidence:(1) Its infrared spectrum shows a single peak at 3247 cm.-l and an amide I1 absorption at 1553 cm.-I, characteristic of secondary amide^.^(2) Its ultraviolet spectrum has maxima at 2330 and 2820 k., characteristic of 2-acyl-1-phenylhydrazines. s (3) Its ethyl ester was cleaved by Raney nickel to give hydantoic acid ethyl ester (VI).