The Journal of Organic Chemistry

The Mechanism of the Acid-Catalyzed Rearrangement of N-Arylaminomethyl Aryl Sulfides

GF Grillot, PTS Lau

文献索引：Grillot,G.F.; Lau,P.T.S. Journal of Organic Chemistry, 1965 , vol. 30, p. 28 - 33

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被引用次数: 10

摘要

Evidence is presented to indicate that the condensation of aromatic thiols, formaldehyde, and aromatic amines in the presence of strong acid results first in the formation of the intermediate products, N-arylaminomethyl aryl sulfides (I) which then rearrange intermolecularly to p-aminobenzyl aryl sulfides (11), a process resembling closely the acid- catalyzed rearrangement of diazoaminobenzenes to p-aminoazobenzenes, Two ...