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Acyloins from t-butylglyoxal

RC Fuson, H Gray, JJ Gouza

文献索引:Fuson; Gray; Gouza Journal of the American Chemical Society, 1939 , vol. 61, p. 1937,1939

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被引用次数: 35

摘要

The condensation of arylglyoxals with aromatic compounds' provides a convenient method for making mixed benzoins. It seemed probable that the method could be used also for acyloins of the type RCOCH (0H) Ar. To test this suggestion we have prepared t- butylglyoxa13 and treated it with aromatic compounds in the presence of aluminum chloride. The expected acyloins were formed in good yields. t-Butylglyoxal (I) was synthesized from ...