Epoxyethers. XVI. A Bicyclo Epoxyether1, 2

CL Stevens, AJ Weinheimer

文献索引：Stevens; Weinheimer Journal of the American Chemical Society, 1958 , vol. 80, p. 4072,4073

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被引用次数: 21

摘要

2, 2, 6-Tritnethylcyclohesanoiie (111) w, s prepared in 69yo over-all yield from carbethoxycyclohexanoiie. Hal (igeiiatiuii of the ketone I11 gave the haloketones IV and V in excellent yield. The chloroketone IV was converted in 839% yield to the bicyclo epoxyether\ TI which was characterized by hydrolysis and reaction with p-nitrobenzoic acid to give the hydroxyketone IX and the ketoberizoate VIII. The structure of the hydrosyketone IX was ...