Reactions of diazo esters with electron-deficient alkenes in the presence of Lewis acids

RA Novikov, DN Platonov, VA Dokichev…

文献索引：Novikov; Platonov; Dokichev; Tomilov; Nefedov Russian Chemical Bulletin, 2010 , vol. 59, # 5 p. 984 - 990

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被引用次数: 10

摘要

Abstract 1, 3-Dipolar cycloaddition reaction of diazo esters to electron-deficient dipolarophiles to yield the corresponding 1-or 2-pyrazolines was found to be significantly accelerated with Lewis acids (Yb (OTf) 3, Sc (OTf) 3, GaCl 3, EtAlCl 2). The use of GaCl 3 as the catalyst leads to the acceleration not only of the 1, 3-dipolar cycloaddition reaction, but also subsequent insertion of the CHCO 2 Me electrophilic fragment of methyl diazoacetate ...