Aerobic Palladium (II)??Catalyzed 5??endo??trig Cyclization: An Entry into the Diastereoselective C??2 Alkenylation of Indoles with Tri??and Tetrasubstituted Double Bonds

SR Kandukuri, JA Schiffner…

文献索引：Kandukuri, Sandeep R.; Schiffner, Julia A.; Oestreich, Martin Angewandte Chemie - International Edition, 2012 , vol. 51, # 5 p. 1265 - 1269

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被引用次数: 43

摘要

The Mizoroki–Heck reaction, that is the palladium (0)-catalyzed alkenylation of prefunctionalized arenes (or alkenes),[1] is now rivaled by oxidative palladium (II)-catalyzed processes (also referred to as Fujiwara–Moritani reactions) that involve CÀH bond activation.[2] These related palladium catalyses proceed through the same CÀC bond- forming step, the migratory insertion of a CÀC double bond into the intermediate C (sp2) ...