Mesityl gold (III) complexes. X-ray structure of mononuclear [Au (mes) 2 Cl (PPh 3)] and the dimer [Au (mes) 2 Cl] 2

…, AJ Edwards, J Garrido, MB Hursthouse…

文献索引：Contel, Maria; Edwards, Andrew J.; Garrido, Julian; Hursthouse, Michael B.; Laguna, Mariano; Terroba, Raquel Journal of Organometallic Chemistry, 2000 , vol. 607, # 1-2 p. 129 - 136

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被引用次数: 19

摘要

The reaction between PPN [AuCl4] and [Hg (mes) 2] gives the anionic complex cis-PPN [Au (mes) 2Cl2](1) and [Hg (mes) Cl] as side-product. Complex 1 is a precursor to other compounds both neutral and cationic. Removal of one chloride ligand affords the mononuclear neutral complexes cis-[Au (mes) 2ClL](L= PPh3 (2), P {p-tol} 3 (3), AsPh3 (4), SPPh3 (5)) by addition of a neutral ligand or, alternatively if no ligand is added, dimeric cis ...